NOTE: In the below, I'm implicitly discussing a ground-state, closed-shell wavefunction, where all occupied orbitals are doubly occupied.The discussion would be similar for open-shell wavefunctions, but there are complexities that I won't address here. What does canonical-form mean? Canonical definition, pertaining to, established by, or conforming to a canon or canons. Triangular canonical form: Let be a linear operator. The Canonical Ensemble Last updated; Save as PDF Page ID 78459; The Boltzmann Distribution; The most practical ensemble is the canonical ensemble with N, V, and T fixed. \$\begingroup\$ @user61001 The actual definition of canonical is a little sophisticated, and it doesn't really apply in this case (although it probably applies in other cases you're thinking of). (mathematics) A standard or normal presentation of a mathematical entity. Canonical ensemble refers to the statistical ensemble that represents possible states of mechanical system in thermal equilibrium having thermal energy reservoir at fixed temperature. This term is borrowed from mathematics, where it is used to refer to concepts that are unique and/or natural. ÈH2 Í≠ÈHÍ2 = È(ÈHÍ≠H)2 ÍπH2. What does canonical form mean? How to use canonical in a sentence. The triangular form, Jordan canonical form and row echelon form are some major canonical forms in Linear Algebra. Search the Dictionary for More Terms. We can imagine a collection of boxes with equal volumes, and equal number of particles. In Minterm, we look for the functions where the output results in “1” while in Maxterm we look for function where the output results in “0”. Canonical Form – In Boolean algebra,Boolean function can be expressed as Canonical Disjunctive Normal Form known as minterm and some are expressed as Canonical Conjunctive Normal Form known as maxterm . The standard representation of canonical form is used in many fields like Linear algebra, graph theory, Operations Research, Computer science, and so on. The word is just misused, in some sense, to mean "natural", "obvious", or "dictated by circumstances". See more. Return to top of page. Definition of canonical form in the Definitions.net dictionary. Information and translations of canonical form in the most comprehensive dictionary definitions resource on the web. \$\endgroup\$ – Alex Youcis Sep 11 '13 at 8:10 The entire collection is … (noun) ... (chemistry) Any of a set of ... be remarked that the counting of constants is not a sure guide to the existence of a conjectured canonical form. Canonical definition is - of, relating to, or forming a canon. We can also show that in the canonical ensemble the mean square ﬂuc-tuation of energy is much smaller than average energy squared, i.e. Canonical, in computer science, is the standard state or behavior of an attribute. 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